Quote:
Originally Posted by JayUtah
When a charged particle is absorbed in the shielding, the absorption triggers the release of secondary radiation in the form of braking radiation. An atom's behavior when it absorbs one of these wayward particles causes its electrons to get happy briefly, and then drop back down to their ground states. That drop releases a photon. The wavelength of the photon depends on the atomic mass of the atom that did the absorbing. Lead, steel, beryllium, and other heavy metals (heavy in the sense of physical density as well as atomic mass) happen to emit secondary radiation in the x-ray band, which isn't a good thing.
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I'd like to put some corrections onto this. First, braking radiation (continuous spectrum) and relaxation of electronic (core hole, in the case of x-rays) states (discrete spectrum) are two completely different, actually unrelated phenomena. With respect to x-ray emission from metal surfaces they just happen to occur in roughly the same energy band, but this is mostly by pure coincidence.
The high energy edge of the continuous part (braking) is solely determined by the energy of the impacting particle, its tailing function, i.e. the intensity distribution towards lower photon energies, is mainly governed by the average electron density in the material. The comparison of the spectra of aluminium (low
e--density, rather smooth hill-like distribution) and tungsten (high
e--density, strong peak at the edge, steep decrease towards low energies) at the same influx energy is a prime textbook example for this. The effective cross section of atomic cores may play a similar role, but for electrons at least it seems of less importance. Atomic mass plays no role of its own here.
The energy of core hole relaxation is (sort of) a function of atomic number, but even quite light elements reach the x-ray band. Aluminium anodes are in fact used for normal (i.e. non-soft) x-ray spectroscopy. It appears quite difficult to even reach the soft x-ray band at all, using anode emission. Before the broad availability of suitable synchrotron radiation, tricky thingies like yttrium anodes had to be used for this.
What may be of some relevance here is the competition of x-ray and Auger emission, where instead of a photon yet another electron is emitted. The ratio depends on the atomic number, the Auger effect is most prominent for light elements (carbon is a standard subject of Auger spectroscopy) while heavier elements yield more x-ray emission. This may result in a lower yield of secondary radiation seen in (pseudo) transmission at a given thickness.
So the picture with respect to particle shielding is that materials with moderate electron density, by braking the incoming particles gently, spread the energy over the lower energy range, thus favouring conversion into heat by reabsorption - which is what you finally want. Furthermore light elements tend to emit less x-rays by specific emission (core holes) than heavy elements.
Beryllium, by the way, isn't a heavy metal by atomic mass (9), number (4) or mass density (1.9g/cm
-3 at RT), rather one of the lightest.
And as a last nitpick: atomic
mass is quite irrelevant here, it is the atomic
number that counts, i.e. nuclear charge. Yes, for your explanation they correlate well and
atomic mass has made its way as a dirty idiom, but next time you do mass spectroscopy, you will see the difference. Don't lose your way in the isotopic forrest!
