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Hopefully somebody with more expertize can help you, but for starters, I'm not sure if the efficiency of a solar cell and that of plants doing photosynthesis is directly comparable. I don't know if a leaf would have to be black to be efficiency, because it may be that the process is not the same, i.e. they are not simply using sunlight for it heating potential. It may be acting as a catalyst in the reaction. Also, it may be that the main constraining factor for photovoltaic cells is sunlight, but it's possible that for photosynthesis, there are other constraining factors that are more important, like need for carbon dioxide or water or whatever. So it may be that the efficiency wouldn't be measured in quite the same way.
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