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  #1 (permalink)  
Old 01-June-2008, 10:08 PM
CA_ No2 CA_ No2 is offline
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Angry 2nd Law of Thermodynamics

Normally when a creationist brings up the 2nd Law I just point to the sun to answer them, but its been suggested to me that energy is not enough, that it must be directed

copypasta to follow:
Quote:
For order to increase (or for evolution not to violate the second law) requires four fundamental conditions. We must have:

1.An open system (which is the case for earth)
2.An available energy source (in our case the sun)
3.A computer-like programmed language to direct the increase in complexity (information theory).
4.A mechanism by which incoming energy may be stored and harnessed.

Therefore to grow from an embryo into a fully grown adult does not violate the second law of thermodynamics because we already have the information programmed into our cells and a mechanism to harness the energy to allow this to proceed. This allows an organism to increase in complexity faster than it could be broken down (as it would have been if left to itself).

Humans and animals traditionally employ metabolic factors to harness the incoming raw energy and thus convert it into usable energy. Plants, on the other hand, harness the incoming raw energy by photosynthesis.

Simply having a supply of raw energy is not sufficient to produce the specified complexity of a living organism – the energy has to be harnessed and subsequently directed. An example often posed to me is that of a freezer unit and its ability to produce ice cubes. However, this would simply not be the case if electrical energy was simply ‘pumped’ into water, would it? Rather, the intense heat produced would tend to break down the present water into its primitive components.

Heat is released into the environment when ice freezes, and so the entropy in the environment increases. If the temperature decreases to below a critical value, the decrease in order compensates for the increasing order in the forming ice cube. To produce the primary building blocks of life – proteins and nucleic acids (from primitive amino acids & nucleotides) would lower the entropy and also remove heat energy (entropy) from the surrounding environment. Therefore evolution does indeed break the second law of thermodynamics because amino acids & nucleotides cannot form spontaneously no matter how much energy in the form of heat (or otherwise) is applied.



Can anyone here tell me whether or not A mechanism by which incoming energy may be stored and harnessed Is actually required by thermodynamics? If it is needed, what other ways can I counter this argument?
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Old 01-June-2008, 10:13 PM
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I believe that's called the first law of thermodynamics.
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Old 01-June-2008, 10:38 PM
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Sorry, we're discussing The second law of thermodynamics as it applies to entropy. I should have made that clearer, my bad.
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Old 02-June-2008, 08:23 AM
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Van Rijn Van Rijn is offline
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This is amusing:

Quote:
Therefore evolution does indeed break the second law of thermodynamics because amino acids & nucleotides cannot form spontaneously no matter how much energy in the form of heat (or otherwise) is applied.
I guess they aren't familiar with the "prebiotic soup" experiments. Quoting from:

http://en.wikipedia.org/wiki/Miller-Urey_experiment

Quote:
The experiment used water (H2O), methane (CH4), ammonia (NH3) and hydrogen (H2). The chemicals were all sealed inside a sterile array of glass tubes and flasks connected together in a loop, with one flask half-full of liquid water and another flask containing a pair of electrodes. The liquid water was heated to induce evaporation, sparks were fired between the electrodes to simulate lightning through the atmosphere and water vapor, and then the atmosphere was cooled again so that the water could condense and trickle back into the first flask in a continuous cycle.

At the end of one week of continuous operation Miller and Urey observed that as much as 10-15% of the carbon within the system was now in the form of organic compounds. Two percent of the carbon had formed amino acids, including 2-3 of the 22 that are used to make proteins in living cells, with glycine as the most abundant. Sugars, lipids, and some of the building blocks for nucleic acids were also formed.

[snip]

This experiment inspired many experiments in a similar vein. In 1961, Joan Oró found that amino acids could be made from hydrogen cyanide (HCN) and ammonia in a water solution. He also found that his experiment produced a large amount of the nucleotide base adenine. Experiments conducted later showed that the other RNA and DNA bases could be obtained through simulated prebiotic chemistry with a reducing atmosphere.

(emphasis added)
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Old 02-June-2008, 10:52 AM
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Quote:
For order to increase (or for evolution not to violate the second law) requires four fundamental conditions.
This is a false assumption from the start.
The second law of thermodynamics only states that total usable thermal energy in a closed system decreases over time. It has nothing to do with "order", why does he think it's called THERMODYNAMICS!
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Old 02-June-2008, 12:18 PM
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Because Thermodynamics referrs also to entropy, or disorder?

Well thats what we were taught, with IIRC entropy being given the symbol S
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Old 02-June-2008, 12:28 PM
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Arguing with creationists is only self-instructive for the first few weeks. After that, it's just pointless.

They made these arguments to others before. They've probably been debunked before. Many of them probably even have an inkling of why this particular argument is wrong, and they're going to make it anyways. There is a creationist behind him/her who is going to try his luck battling a "Darwinist" and is going to restart the cycle by making the same argument.
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Old 02-June-2008, 12:44 PM
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In answer to this particular series of arguments:
Quote:
1.An open system (which is the case for earth)
2.An available energy source (in our case the sun)
Yes. Earth is an open system. In order for there to be useable energy available to a system "indefinitely", it needs to have a "hot well" (the sun) and a "cold well" (non-sun-pointing space). Other hot and cold wells are available in other local areas, such as undersea hydrothermal vents, and other energy cycles exist there.

Quote:
3.A computer-like programmed language to direct the increase in complexity (information theory).
I don't think this is true. It is the case that life has a complex "computer-like" information storage mechanism (several of them! DNA, RNA, protien rings). But all that is necessary for entropy to decrease, for anyone who has studied thermodynamics, is some sort of matter - any sort of matter at all! A gas, the most disorderly chemical energy state has an entropy state associated with other thermodynamic variables (it's thermodynamic state is determined by any two of them). A heat engine goes through an entropy cycle with said gas - refrigeration, car engines, ect, wouldn't work otherwise. Gas certainly isn't a complex computer-like information storage mechanism, but on the level that thermodynamics operates it is sufficeint. Furthermore, "entropy" in information theory may bear superficial resemblance to "entropy" in thermodynamics, hence the similar name, but the link between the two isn't well established. Confusing the two is nonsense.
Quote:
4.A mechanism by which incoming energy may be stored and harnessed.
The only storage mechanism necessary for entropy in an open system to increase or decrease is for objects to get hot or cold. Other storage mechanisms are just bonus points on top of this.


The lifeless gas in a planetary climate system produces "complexity" up to a point, and local entropy/energy cycles, just by being in an open system with a hot and cold well.
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Old 02-June-2008, 01:09 PM
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The second law of thermodynamics applies to closed (therefore finite), isolated systems. I am not sure the interplay between gravity and heat dissipation and whatever is causing what is perceived to be cosmological expansion is well accounted for in terms of entropy growth. Gravitational force opposes the increase of entropy associated with the heating of a collapsing proto-stellar cloud in which very large ion currents have formed giving rise to very large magnetic fields, and on some scale all of this is affected by the tendency of space (or some intrinsic spacebound [Higgs] field) to expand. Each of these very strong effects will vary over time in some stochastic manner and the interplay of neutrinos, gravitons, and photons and the influence of dark matter and dark energy ensures that there are no isolated systems in the observable universe nor in the physical universe unless some portions of it were mutually isolated during the inflation epoch.

My guess is that we must quantify the causes of cosmological expansion and gain a much better understanding than we (certainly I) currently have about how the usual suspects play together before we can appreciate the limits on entropy growth.
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Old 02-June-2008, 02:00 PM
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In a way, the statement that it requires those four things is accurate, but only if you interpret numbers 3 and 4 in a way that the Creationist speaker did not realize was possible.

#4 is simple enough. Every single time energy moves anywhere or undergoes any kind of transformation, it's being either "stored" or "harnessed". It could never really not be doing one of those two things. So as soon as the energy flow in any closed or non-closed "system" is described, there's your storage and harnessing: it's in everything the energy did every step of the way.

#3 seems to be what they usually describe as a source of "information", something that restricts the countless hypothetically possible outcomes, most of which are rather disordered, and "chooses" one of the relatively few that are more ordered. But what they don't consider is that that input source doesn't need to be a programmer living outside the system; in certain cases the laws of physics, geometry, and natural selection have the same effect. THEY, the laws of nature, are the mysterious guiding input you're looking for that makes certain outcomes more likely than others and more likely than they'd be by pure randomness alone.
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