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Old 24-June-2008, 02:43 PM
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Default The state of glass

Saw this on the news...
Scientists reveal why glass is glass

I've never got a good grasp on the debate of whether glass is a liquid or a solid.
I looked for a discussion, but there's only references and not a whole discussion.
Here is mention (also per wiki) that it is an amorphous solid.

The article claims to solve exactly what it is:
Quote:
The breakthrough involved solving the decades-old problem of just what glass is.
Considering they reference this...
Quote:
The deceptively liquid-like behavior of glass can be seen when you look at glass in the windows of an old building. The glass begins to sag and distort internally over the centuries, due to the effect of gravity.
...which I always thought was an urban legend (that the glass was always imperfect and installed thick side down)
It makes me think that the article is suspect in some ways.

Any thoughts or comments?
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Old 24-June-2008, 03:12 PM
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It is suspect - you are right. The reason older glass varies in thickness is because of how it was made back then. The Pilkington method of "float glass" yields the uniform-thickness glass.

I live near Corning so I've seen this: Glass panes originated from a large cylinder of glass that was spun flat - so you can imagine the outer endges would be thinner than the inner. hence the variance in glass thickness. That's oversimplified but it sums it up.
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Old 24-June-2008, 03:39 PM
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What LotusExcelle said. And the reason that the glass in old buildings is thicker on the bottom - if you were putting a piece of glass in a window frame, how would you put it? With the thicker part down.

As far as glass being a solid or a liquid... I say it is glass, which has properties different than either a crystalline solid or a liquid. But if you have to pick, I pick solid.
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Old 24-June-2008, 05:22 PM
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glass is referred to as "soft condensed material"
Quote:
Scientists fully understand the process of water turning to ice. As the temperature cools, the movement of the water molecules slows. At 32 F, the molecules form crystal lattices, solidifying into ice. In contrast, the molecules of glasses do not crystallize. The movement of the glass molecules slows as temperature cools, but they never lock into crystal patterns. Instead, they jumble up and gradually become glassier, or more viscous. No one understands exactly why.
more here:

http://www.sciencedaily.com/releases...0809130014.htm
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Old 24-June-2008, 05:25 PM
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I pick fluid. It's not an urban legend - the panes of old windows are thicker at the bottom and I really don't think it is because they were installed that way.

Smaller panes of glass are normally cut from a larger sheet.
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Old 24-June-2008, 05:27 PM
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Geonuc - the pane thickness difference has to do with how those panes were made. Float glass didn't exist and the way they were made meant that they all have varying thickness. Go to Corning - they have some glass cylinders in various stages of making panes. And you can see the process by which this happens. Let me see if I can find a link... i'll post later.
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Old 24-June-2008, 05:34 PM
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I change my vote.

http://dwb.unl.edu/Teacher/NSF/C01/C...indowpane.html
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Old 24-June-2008, 05:36 PM
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Very glad to see you researched it! And even more glad that you changed your opinion - I think we all know how often people are stubborn. Very refreshing!
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Old 24-June-2008, 06:07 PM
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I can be stubborn, too.
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Old 24-June-2008, 06:12 PM
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Oh me too - I think its a rather common fault.
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Old 24-June-2008, 08:33 PM
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I remember reading somewhere many years ago that glass actually drips every 800 years.

But let's face it, if it feels solid, even takes more than a month to drip, and it shatters if you hit it on something, then it's a solid.
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Old 24-June-2008, 09:10 PM
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If glass was not truly solid, it would make a poor material for telescope mirrors. In a telescope, even the slightest imperfection (much smaller than you could measure with a ruler) ruins the image.
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Old 24-June-2008, 09:51 PM
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Quote:
Originally Posted by Ross PK81 View Post
I remember reading somewhere many years ago that glass actually drips every 800 years.

But let's face it, if it feels solid, even takes more than a month to drip, and it shatters if you hit it on something, then it's a solid.
I'm not sure what you mean by "drips". I don't think most glasses would show any significant dimensional changes in periods of hundreds of years at any temperature close to room temperature, let alone what I think of as "drips".

There have been cases where glass has been chemically attacked, such as from sea water, and the corrosion products can form "drips" down the glass.
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Old 24-June-2008, 10:43 PM
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Roman glass hasn't 'dripped' and there are examples of renaissance glass that haven't sagged or deformed. There is glass in Durham Cathedral that has been there for 900 years.
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Old 25-June-2008, 12:54 AM
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Quote:
Originally Posted by captain swoop View Post
Roman glass hasn't 'dripped' and there are examples of renaissance glass that haven't sagged or deformed. There is glass in Durham Cathedral that has been there for 900 years.
There are pieces of obsidian shaped into points (by humans) that haven't changed in 16,000 years!
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Old 25-June-2008, 02:32 PM
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Lol, guess the book, or newspaper must have been wrong then. Unless they didn't mean actual 'drips', and meant sagging. Then again maybe the drips are minute?
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Old 25-June-2008, 02:35 PM
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Glass does not drip or sag or deform from age in any way over any known length of time. Heat it up and it does stuff but we're talking thousands of degrees. Any information to the contrary is incorrect entirely.
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Old 25-June-2008, 03:26 PM
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Curiously, substances we are quite happy considering as solid - ductile metals for example - "flow" more than window-glass does - consider lead roofing for example. But we call that "creep" and that is considered a property of solids so we are happy with that.

Pitch looks glassy, and shatters like glass when struck. But that truly is a very viscous liquid, and can be shown to drip, even when protected from the sun.

The fact that at sufficiently high pressures/temperatures, there ceases to be a phase transition between liquid and gas should remind us that phases/states can be all rather messy, and we can't expect precise classifications always to work.
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Old 25-June-2008, 07:26 PM
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Nowhere in the article did I see any mention of quartz, which, like glass is SiO2 and, unlike glass, is a true crystalline solid.
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Old 25-June-2008, 08:10 PM
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It might be moderately funny if someone contacts Keck Observatory and tells them that there scope mirrors are liquid and are going to start dripping.
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Old 26-June-2008, 02:57 AM
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Quote:
Originally Posted by Ivan Viehoff View Post
Pitch looks glassy, and shatters like glass when struck. But that truly is a very viscous liquid, and can be shown to drip, even when protected from the sun.
For this see the Pitch Drop Experiment of the University of Queensland.
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